Hybrid Silver Nanoparticles–Purple Sweet Potato (Ipomoea batatas L.) Peels as a Prospective Adsorbent for Bromophenol Blue Removal
Downloads
Water pollution caused by dye effluents has become a global problem, for example in the textile, paper, and food industries. One common type of dye waste is bromophenol blue, which is considered to pose a low level of danger, but frequent exposure to its waste can cause skin irritation. This research was conducted using silver nanoparticles synthesized with purple sweet potato peels, which are rich in anthocyanin content so that it can be used as an active reducing agent and produce an adsorbent used for dye waste removal. Combination of biogenic-chemical method was chosen due to its simplicity, cost-effectiveness, and lower toxicity. Characterization of the obtained nanomaterials included UV-Vis spectroscopy, FTIR, SEM-EDX, and XRD. The results showed that the average crystal size of pure IBpe and the three IBpe-AgNPs were 7.09 nm, 8.68 nm, and 13.99 nm with an FCC crystal shape. The average particle sizes of the three IBpe-AgNPs were 82.76 nm, 85.72 nm, and 99.78 nm, with an almost spherical shape. The research found that IBpe-AgNP 1:9 demonstrated the highest adsorption efficiency of 77.24% compared to the other samples. In terms of desorption efficiency, the IBpe-AgNP 1:3 sample showed the highest value at 27.54% compared to the other three samples. Furthermore, the reuse test revealed that the IBpe-AgNP 1:9 sample had the highest reuse value at 27.02% compared to the other samples, showing the same trend as the first adsorption.
I. A. Aguayo-Villarreal, D. Cortes-Arriagada, C. K. Rojas-Mayorga, K. Pineda-Urbina, R. Muñiz-Valencia, and J. González, “Importance of the interaction adsorbent –adsorbate in the dyes adsorption process and DFT modeling,” J. Mol. Struct., vol. 1203, p. 127398, Mar. 2020, doi: 10.1016/j.molstruc.2019.127398.
V. Katheresan, J. Kansedo, and S. Y. Lau, “Efficiency of various recent wastewater dye removal methods: A review,” J. Environ. Chem. Eng., vol. 6, no. 4, pp. 4676–4697, Aug. 2018, doi: 10.1016/j.jece.2018.06.060.
S. Senthilkumaar, P. Kalaamani, K. Porkodi, P. R. Varadarajan, and C. V. Subburaam, “Adsorption of dissolved Reactive red dye from aqueous phase onto activated carbon prepared from agricultural waste,” Bioresour. Technol., vol. 97, no. 14, pp. 1618–1625, Sep. 2006, doi: 10.1016/j.biortech.2005.08.001.
K. G. Akpomie and J. Conradie, “Efficient synthesis of magnetic nanoparticle-Musa acuminata peel composite for the adsorption of anionic dye,” Arab. J. Chem., vol. 13, no. 9, pp. 7115–7131, Sep. 2020, doi: 10.1016/j.arabjc.2020.07.017.
J. Liu, S. Yao, L. Wang, W. Zhu, J. Xu, and H. Song, “Adsorption of bromophenol blue from aqueous samples by novel supported ionic liquids,” J. Chem. Technol. Biotechnol., vol. 89, no. 2, pp. 230–238, Feb. 2014, doi: 10.1002/jctb.4106.
Q. Liu, “Pollution and Treatment of Dye Waste-Water,” IOP Conf. Ser. Earth Environ. Sci., vol. 514, no. 5, p. 052001, May 2020, doi: 10.1088/1755-1315/514/5/052001.
N. S. Shah et al., “Nano-zerovalent copper as a Fenton-like catalyst for the degradation of ciprofloxacin in aqueous solution,” J. Water Process Eng., vol. 37, p. 101325, Oct. 2020, doi: 10.1016/j.jwpe.2020.101325.
M. N. Zafar, Q. Dar, F. Nawaz, M. N. Zafar, M. Iqbal, and M. F. Nazar, “Effective adsorptive removal of azo dyes over spherical ZnO nanoparticles,” J. Mater. Res. Technol., vol. 8, no. 1, pp. 713–725, Jan. 2019, doi: 10.1016/j.jmrt.2018.06.002.
A. I. Abd-Elhamid et al., “Enhanced removal of cationic dye by eco-friendly activated biochar derived from rice straw,” Appl. Water Sci., vol. 10, no. 1, p. 45, Jan. 2020, doi: 10.1007/s13201-019-1128-0.
K. G. Akpomie and J. Conradie, “Biosorption and regeneration potentials of magnetite nanoparticle loaded Solanum tuberosum peel for celestine blue dye,” Int. J. Phytoremediation, vol. 23, no. 4, pp. 347–361, Mar. 2021, doi: 10.1080/15226514.2020.1814198.
M. Pita, K. J. Fernández-Andrade, S. Quiroz-Fernández, J. M. Rodríguez-Díaz, and C. A. Díaz, “Assessment of biomass as an effective adsorbent for the removal of pharmaceutical compounds: A literature review,” Case Stud. Chem. Environ. Eng., vol. 9, p. 100596, Jun. 2024, doi: 10.1016/j.cscee.2023.100596.
J. Bayuo, M. Rwiza, and K. Mtei, “A comprehensive review on the decontamination of lead( II ) from water and wastewater by low-cost biosorbents,” RSC Adv., vol. 12, no. 18, pp. 11233–11254, 2022, doi: 10.1039/D2RA00796G.
Md. R. Khan, S. M. Hoque, K. F. B. Hossain, Md. A. B. Siddique, Md. K. Uddin, and Md. M. Rahman, “Green synthesis of silver nanoparticles using Ipomoea aquatica leaf extract and its cytotoxicity and antibacterial activity assay,” Green Chem. Lett. Rev., vol. 13, no. 4, pp. 303–315, Oct. 2020, doi: 10.1080/17518253.2020.1839573.
G. Das, J. K. Patra, N. Basavegowda, Chethala. N. Vishnuprasad, and H.-S. Shin, “Comparative study on antidiabetic, cytotoxicity, antioxidant and antibacterial properties of biosynthesized silver nanoparticles using outer peels of two varieties of Ipomoea batatas (L.) Lam,” Int. J. Nanomedicine, vol. Volume 14, pp. 4741–4754, Jul. 2019, doi: 10.2147/IJN.S210517.
C. R. Silva-Correa et al., “Potential Anticancer Activity of Bioactive Compounds from Ipomoea batatas,” Pharmacogn. J., vol. 14, no. 3, pp. 650–659, Jun. 2022, doi: 10.5530/pj.2022.14.84.
E. Rohaeti, “Application of Silver Nanoparticles Synthesized by Using Ipomoea batatas L. Waste to Improve Antibacterial Properties and Hydrophobicity of Polyester Cloths”.
Y. R. Im, I. Kim, and J. Lee, “Phenolic Composition and Antioxidant Activity of Purple Sweet Potato (Ipomoea batatas (L.) Lam.): Varietal Comparisons and Physical Distribution,” Antioxidants, vol. 10, no. 3, p. 462, Mar. 2021, doi: 10.3390/antiox10030462.
K. G. Akpomie and J. Conradie, “Biogenic and chemically synthesized Solanum tuberosum peel–silver nanoparticle hybrid for the ultrasonic aided adsorption of bromophenol blue dye,” Sci. Rep., vol. 10, no. 1, p. 17094, Oct. 2020, doi: 10.1038/s41598-020-74254-y.
S. Zhu, H. Sun, T. Mu, Q. Li, and A. Richel, “Preparation of cellulose nanocrystals from purple sweet potato peels by ultrasound-assisted maleic acid hydrolysis,” Food Chem., vol. 403, p. 134496, 2023, doi: https://doi.org/10.1016/j.foodchem.2022.134496.
K. Ranoszek-Soliwoda et al., “The role of tannic acid and sodium citrate in the synthesis of silver nanoparticles,” J. Nanoparticle Res., vol. 19, no. 8, p. 273, Aug. 2017, doi: 10.1007/s11051-017-3973-9.
B. J. Wiley, S. H. Im, Z.-Y. Li, J. McLellan, A. Siekkinen, and Y. Xia, “Maneuvering the Surface Plasmon Resonance of Silver Nanostructures through Shape-Controlled Synthesis,” J. Phys. Chem. B, vol. 110, no. 32, pp. 15666–15675, Aug. 2006, doi: 10.1021/jp0608628.
K. Okaiyeto, M. O. Ojemaye, H. Hoppe, L. V. Mabinya, and A. I. Okoh, “Phytofabrication of Silver/Silver Chloride Nanoparticles Using Aqueous Leaf Extract of Oedera genistifolia: Characterization and Antibacterial Potential,” Molecules, vol. 24, no. 23, p. 4382, Nov. 2019, doi: 10.3390/molecules24234382.
Th. B. Devi and M. Ahmaruzzaman, “Bio-inspired sustainable and green synthesis of plasmonic Ag/AgCl nanoparticles for enhanced degradation of organic compound from aqueous phase,” Environ. Sci. Pollut. Res., vol. 23, no. 17, pp. 17702–17714, Sep. 2016, doi: 10.1007/s11356-016-6945-1.
Copyright (c) 2025 Mirza Ardella Saputra

This work is licensed under a Creative Commons Attribution 4.0 International License.
Copyright
Journal of Advanced Technology and Multidiscipline (E-ISSN:2964-6162) by Universitas Airlangga, Faculty of Advanced Technology and Multidiscipline is licensed under a Creative Commons ” Attribution 4.0 International ” CC BY 4.0
Authors who publish with this journal agree to the following terms:
-
The journal allows the author to hold the copyright of the article without restrictions.
-
The journal allows the author(s) to retain publishing rights without restrictions.
-
The legal formal aspect of journal publication accessibility refers to Creative Commons Attribution (CC BY).
LICENSE TERMS
You are free to:
- Share ” copy and redistribute the material in any medium or format
- Adapt ” remix, transform, and build upon the material for any purpose, even commercially.
Under the following terms:
-
Attribution ” You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
- No additional restrictions ” You may not apply legal terms or technological measures that legally restrict others from doing anything the license permits