POTENSI EKSTRAK DAUN SALAM (Syzygium polyanthum) PADA pH ASAM SEBAGAI SENSITIZER PADA DYE SENSITIZED SOLAR CELL (DSSC)
Downloads
Penelitian dilakukan untuk mengetahui potensi ekstrak daun salam (Syzygium polyanthum) dalam pH asam sebagai sensitizer pada DSSC. Pada penelitian ini teknik ekstraksi yang digunakan adalah teknik maserasi. Sampel ekstrak daun salam dikarakterisasi dengan menggunakan alat instrumen Spektrofotometer UV-Vis dan Voltameter Siklik untuk mengetahui potensi yang dihasilkan oleh molekul zat warna tersebut sebagai sansitizer pada DSSC. Dari spektrum serapan UV-Vis diketahui bahwa ekstrak daun salam mengandung pigmen klorofil, hal ini dikarenakan puncak serapan maksimal ekstrak daun salam berada pada panjang gelombang 468,50 nm yang diduga merupakan klorofil a dan 662, 50 nm yang diduga merupakan klorofil b. Dari karakterisasi dengan menggunakan voltameter siklik didapatkan hasil terbaik pada ekstrak daun salam pH 1 dengan energi gap sebesar 0,60699 eV.
Al-Alwani MAM, M. A, 2015. Effect of solvents on the extraction of natural pigments and adsorption onto TiO2 for dye-sensitized solar cell applications. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 130-137.
Al-Alwani, M. A., Mohamad, A. B., Kadhum, A. A., Ludin, N. A., Safie, N. E., Razali, M. Z., Sopian, K., 2017. Natural dye extracted from Pandannus amaryllifolius leaves as sensitizer in fabrication of dye-sensitized solar cells. Int. J. Electrochem. Sci.,, 747-761.
Aryanti., N., 2016. Ekstraksi Dan Karakterisasi Klorofil Dari Daun Suji (Pleomele Angustifolia) Sebagai Pewarna Pangan Alami. J. Apl. Teknol. Pangan, 129-135.
Ayele, W. A., 2016. Dye-sensitized solar cells using natural dye as light-harvesting materials extracted from Acanthus sennii chiovenda flower and Euphorbia cotinifolia leaf. J. Sci. Adv. Mater. Devices, 488-494.
Aziza Hfii Ahliha, F. N., 2018. Kajian pH Klorofil Terhadap Ikatan Kimia Dye pada TiO2 sebagai Aplikasi Dye-Sensitized Solar Cell (DSSC). Jurnal Fisika dan Aplikasinya, 16-19.
D. Ganta, J. J., 2017. Dye-sensitized solar cells using Aloe Vera and Cladode of Cactus extracts as natural sensitizers. Chem. Phys. Lett, 97-101.
D. Sinha, D. D., 2020. Photo sensitizing and electrochemical performance analysis of mixed natural dye and nanostructured ZnO based DSSC. Sadhana - Acad. Proc. Eng. Sci., 175.
Grätzel, B. O., 1991. A low-cost, high-efficiency solar cell based on dye sensitized colloidal TiO2 films. Nature, 353, 737–740.
Grätzel, M., 2003. Dye-sensitized solar cells. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 4(2), 145-153.
Gusiak, N. K., 2011. Organik Dye Sensitisers For Solar Cells And Semikonduktor Photocatalysts- A Method For Suitability Evaluation Explained. . Biblioteka Cyfrowa Polithechniki Krakowskiej, 60-73.
J. Bisquert, J. G.-C., 2003. Comparative analysis of photovoltaic principles governing dye-sensitized solar cells and p-n junctions. Journal Spin Use 6, 5215.
J. Gong, K. S., 2017. Review on dye-sensitized solar cells (DSSCs). Advanced techniques and research trends. Renew Sustain. Energy Rev, 234-246.
K. Sharma, V. S., 2018. Dye-Sensitized Solar Cells: Fundamentals and Current Status. Nanoscale Res. Lett, 381.
K. Tennakone, G. K., 1996. Efficient photosensitization of nanocrystalline TiO2 films by tannins and related phenolic substances. Journal of Photochemistry & Photobiology.
K. Wongcharee, V. M., 2007. Sol. Energy Mater. Sol. Cells.
L. G. Oktariza, B. Y., 2018. Performance of dye sensitized solar cells (DSSC) using Syngonium Podophyllum Schott as natural dye and counter electrode. AIP Conf. Proceeding, (p. 1958).
M. A. M. Al-Alwani, A. B., 2019. Performance of the dye-sensitized solar cells fabricated using natural dyes from Ixora coccinea flowers and Cymbopogon schoenanthus leaves as sensitizers. Int. J. Energy Res., 7229-7239.
M.M. Noor, M. B., 2011. Int. J.Photoenergy, 5.
Milne, F. B., Toker, Y., Rubio, A., & Nielsen, a. S, 2015. Unraveling the intrinsic Color of Chlorophyll. Angewandte Chemie International Edition 54, 2170-2173.
Muhandri., D. R., 2019. Pengaruh Fortifikasi Zat Besi Menggunakan Fe-Sulfat , Fe-Fumarat dan Na Fe EDTA Terhadap Kualitas Sensori Produk-Produk Olahan Tepung Terigu The Effect of Iron Fortification using Fe-Sulfat , Fe-Fumarata and Na Fe EDTA on Sensory Quality of Wheat Products. Jurnal IPB, 54-62.
Prajitno., I. H., 2015. Pengaruh Penggunaan Gel-Electrolyte pada Prototipe. J. SAINS DAN SENI ITS, 2337-3520.
R. Amelia, D. D., 2014. Fabrikasi Dye Sensitized Solar Cell (DSSC) dengan Sintesis Dye Komposit dari Garcinia mangostana, Celosia cristata, Beta vulgaris rubra dan Musa aromatica pada Fraksi Volume. J. Tek. POMITS, 1-5.
Rendy Rohmatul Maulid, A. N., 2015. Kadar Total Pigmen Klorofil dan Senyawa Antosianin Ekstrak Kastuba (Euphorbia pulcherrima) Berdasarkan Umur Daun. Seminar Nasional Konservasi dan Pemnafaatan Sumber Daya Alam 2015, 225-230.
Rimbi Rodiyana Sova and Pirim Setiarso., 2021. Studi Elektrokimia Klorofil dan Antosianin Sebagai Fotosensitizer DSSC (Dye-Sensitized Solar Cell). UNESA Journal of Chemistry, 191-199.
Rossi., M., 2017. Chlorophylls and xanthophylls of crop plants as dyes for Dye-Sensitized Solar Cells (DSSC). J.Plant Sci. Phytopathol., 087-094.
S. Kim, J. L., 2006. J. Am. Chem. Soc, 128.
S. R. Alfidharisti, F. N., 2017. . Influence of electrode spacing on the efficiency of dye-sensitized solar cell. J. Phys. Conf. Ser., 36-40.
Setiarso., A. S., 2016. Pembuatan Elektroda Pasta Karbon Termodifikasi Zeolit Untuk Analisis Fenol Secara Cyclic Stripping Voltammetry. UNESA J. Chem, 86-93.
Sumenda, L., 2011. Analisis Kandungan Klorofil Daun Mangga (Managifera Indica L.) Pada Tingkat Perkembangan Daun Yang Berbeda. Bioslogos, 1.
Syafinara, R., Gomesh, N., Irwanto, M., Fareq, M., & Irwan, Y., 2015. Chlorophyll Pigments as Nature Based Dye for Dye-Sensitized Solar Cell (DSSC). Energy Procedia, 896-902.
Sze, S., 2001. Semikonduktor devices Physics and Technology 2nd. Taiwan: Printed in the United States of America.
Copyright (c) 2021 Jurnal Kimia Riset
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
COPYRIGHT NOTICE
1. By submitting the article to Jurnal Kimia Riset (JKR), the author has agreed to transfer some of the copyrights to the publisher of the research chemistry journal, Universitas Airlangga, indicated in the Copyright Transfer Agreement.
2. Authors still retain significant rights to use and share their own published articles for non-commercial purposes subject to Creative Commons Attribution-NonComercial 4.0 International License
3. All publications (printed/electronic) are open access for educational purposes, research, library, and other non-commercial purposes. Besides the purposes mentioned above, the editorial board is not responsible for copyright violations.
