REPARASI DAN KARAKTERISASI ALFA-Fe2O3 /ZEOLIT Y UNTUK REAKSI PERENGKAHAN ASAM PALMITAT
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Telah dilakukan preparasi dan karakterisasi a-Fe2O3/zeolite Y sebagai katalis uji reaksi perengkahan asam palmitat. Zeolit A disintesis dari NaOH, NaAlO2 dan TEOS dengan metode kristalisasi bertahap. Katalis alfa-Fe2O3/zeolite Y disiapkan melalui metode impregnasi menggunakan larutan Fe(NO3)3 1 M dan proses kalsinasi pada suhu 500 oC dengan dialiri gas N2 selama 5 jam. Katalis dikarakterisasi dengan XRD, FTIR dan surface area analyzer menggunakan metode BET. Uji aktivitas katalis dilakukan pada suhu 380 – 400 oC. Analisis GC-MS terhadap hasil reaksi perengkahan menunjukkan terbentuknya senyawa-senyawa hidrokarbon seperti alkana dan alkena yang memiliki rantai karbon lebih pendek dari asam palmitat atau biogasoline
Abdulloh, A., Maryam, S., Aminah, N. S., Triyono, T., Trisunaryanti, W., Mudasir, M., and Prasetyoko, D. (2014). Modification of turen's bentonite with AlCl3 for esterification of palmitic acid. Bulletin of Chemical Reaction Engineering and Catalysis, 9(1), 66–73.
Godhani, D. R., Nakum, H. D., Parmar, D. K., Mehta, J. P., and Desai, N. C. (2017). Zeolite Y encaged Ru(III) and Fe(III) complexes for oxidation of styrene, cyclohexene, limonene, and α-pinene: An eye-catching impact of H2SO4 on product selectivity. Journal of Molecular Catalysis A: Chemical, 426, 223–237.
Huang, Y., Wang, K., Dong, D., Li, D., Hill, M. R., Hill, A. J., and Wang, H. (2010). Synthesis of hierarchical porous zeolite NaY particles with controllable particle sizes. Microporous and Mesoporous Materials, 127(3), 167–175.
Jiang, J., Jorda, J. L., Yu, J., Baumes, L. A., Mugnaioli, E., Diaz-Cabanas, M. J., and Corma, A. (2011). Synthesis and Structure Determination of the Hierarchical Meso-Microporous Zeolite ITQ-43. Science, 333(6046), 1131–1134.
Liu, Y., Yao, L., Xin, H., Wang, G., Li, D., and Hu, C. (2015). The production of diesel-like hydrocarbons from palmitic acid over HZSM-22 supported nickel phosphide catalysts. Applied Catalysis B: Environmental, 174–175, 504–514.
Lokhande, S., Doggali, P., Rayalu, S., Devotta, S., and Labhsetwar, N. (2015). High catalytic activity of Pt–Pd containing USY zeolite catalyst for low temperature CO oxidation from industrial off gases. Atmospheric Pollution Research, 6(4), 589–595.
Prado, C. M. R., and Antoniosi Filho, N. R. (2009). Production and characterization of the biofuels obtained by thermal cracking and thermal catalytic cracking of vegetable oils. Journal of Analytical and Applied Pyrolysis, 86(2), 338–347.
Sadeghbeigi, R. (2012). Fluid Catalytic Cracking Handbook: An Expert Guide to the Practical Operation, Design, and Optimization of FCC Units. Elsevier Science.
Sihombing, M. (2017). Konsumsi bbm paruh pertama 2017 naik, http://industri.bisnis.com/read/20170816/44/681587/konsumsi-bbm-paruh-pertama-2017-memben, diakses 3 Oktober 2017
Tong, G., Guan, J., Xiao, Z., Huang, X., and Guan, Y. (2010). In situ generated gas bubble-assisted modulation of the morphologies, photocatalytic, and magnetic properties of ferric oxide nanostructures synthesized by thermal decomposition of iron nitrate. Journal of Nanoparticle Research, 12(8), 3025–3037.
Weitkamp, J., and Puppe, L. (1999). Catalysis and Zeolites: Fundamentals and Applications. Springer Berlin Heidelberg.
Zuhri, S. (2017). Impor minyak dan BBM RI bakal terus meningkat, http://industri.bisnis.com/read/20170426/44/648331/impor-minyak-bbm-ri-bakal-terus-meningkat, diakses tanggal 3 Oktober 2017
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